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Creators/Authors contains: "Rader, Shelby T."

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  1. Heavy metal contamination in urban environments, particularly lead (Pb) pollution, is a health hazard both to humans and ecological systems. Despite wide recognition of urban metal pollution in many cities, there is still relatively limited research regarding heavy metal distribution and transport at the household-scale between soils and indoor dusts—the most important scale for actual human interaction and exposure. Thus, using community-scientist-generated samples in Indianapolis, IN (USA), we applied bulk chemistry, Pb isotopes, and scanning electron microscopy (SEM) to illustrate how detailed analytical techniques can aid in interpretation of Pb pollution distribution at the household-scale. Our techniques provide definitive evidence for Pb paint sourcing in some homes, while others may be polluted with Pb from past industrial/vehicular sources. SEM revealed anthropogenic particles suggestive of Pb paint and the widespread occurrence of Fe-rich metal anthropogenic spherules across all homes, indicative of pollutant transport processes. The variability of Pb pollution at the household scale evident in just four homes is a testament to the heterogeneity and complexity of urban pollution. Future urban pollution research efforts would do well to utilize these more detailed analytical methods on community-sourced samples to gain better insight into where the Pb came from and how it currently exists in the environment. However, these methods should be applied after large-scale pollution screening techniques such as portable X-ray fluorescence (XRF), with more detailed analytical techniques focused on areas where bulk chemistry alone cannot pinpoint dominant pollution mechanisms and where community scientists can also give important metadata to support geochemical interpretations. 
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  2. The formation of continental crust via plate tectonics strongly influences the physical and chemical characteristics of Earth’s surface and may be the key to Earth’s long-term habitability. However, continental crust formation is difficult to observe directly and is even more difficult to trace through time. Nontraditional stable isotopes have yielded significant insights into this process, leading to a new view both of Earth’s earliest continental crust and of what controls modern crustal generation. The stable isotope systems of titanium (Ti), zirconium (Zr), molybdenum (Mo), and thallium (Tl) have proven invaluable. Processes such as fractional crystallization, partial melting, geodynamic setting of magma generation, and magma cooling histories are examples of processes illuminated by these isotope systems. 
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